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Functionalised polymeric materials in the efficient synthesis of 2-substituted η3-butadienyl molybdenum complexes (2023)
Journal Article

Polystyrene resins functionalised with phosphonium chloride or bromide have been found to function as efficient catalysts in the synthesis of complexes of the type [MoCl(CO)2(h3-CH2C(COCl)C=CH2)L2], the rate of conversion being controlled by the stru... Read More about Functionalised polymeric materials in the efficient synthesis of 2-substituted η3-butadienyl molybdenum complexes.

Stepwise, non-adherent differentiation of human pluripotent stem cells to generate basal forebrain cholinergic neurons via hedgehog signaling (2013)
Journal Article

Basal forebrain cholinergic neurons (bfCNs) which provide innervation to the hippocampus and cortex, are required for memory and learning, and are primarily affected in Alzheimer's Disease (AD), resulting in related cognitive decline. Therefore gener... Read More about Stepwise, non-adherent differentiation of human pluripotent stem cells to generate basal forebrain cholinergic neurons via hedgehog signaling.

One pot synthesis of η3-butadienyl complexes of Mo(II) or W(II): Crystal structure of [MoCl(CO)2(η3-CH2C(CONHCH2Ctriple bondCH)Cdouble bondCH2)(2,2′-bipyridine)] (2006)
Journal Article

A one pot reaction of [M(CO)4L2] (M = Mo, L2 = 2,2′-bipyridine, 1,10-phenanthroline; M = W, L2 = 2,9-dimethyl-1,10-phenanthroline) with 1,4-dichloro-2-butyne and Ph4PCl was examined in chlorinated solvents over the range 40–129 °C. Production of eith... Read More about One pot synthesis of η3-butadienyl complexes of Mo(II) or W(II): Crystal structure of [MoCl(CO)2(η3-CH2C(CONHCH2Ctriple bondCH)Cdouble bondCH2)(2,2′-bipyridine)].

Effect of substituents on the molybdenum mediated carbonylation and methoxycarbonylation of dihaloalkynes (2006)
Journal Article

Dihaloalkynes of the type YCH(R)CtripleCCH(R)Y or YCMe2CtripleCCMe2Y (Y=Cl, Br, I) were prepared from their diol precursors and reacted with [Mo(CO)3(phen)Y]-. Formation and stability of the substituted products of the type [Mo(CO)2(h3-CH(R)C(COX)C=C... Read More about Effect of substituents on the molybdenum mediated carbonylation and methoxycarbonylation of dihaloalkynes.

Solvent-controlled formation of η3-butadienyl or η3-allyl group 6 transition metal complexes in water or alcohols (2004)
Journal Article

Preparation of acyl chloride, ester, amide or thioester-substituted η3-butadienyl complexes of the type [MCl(CO)2(η3-CH2C(COXR)CCH2)(L2)] (M=Mo,W; XR=Cl, OR, NHR, SR; L2=1,10-phenanthroline (phen), 2,9-dimethyl-1,10-phenanthroline) from 1,4-dichloro-... Read More about Solvent-controlled formation of η3-butadienyl or η3-allyl group 6 transition metal complexes in water or alcohols.

Synthesis and reactivity of organochalogen ester substituted η3-butadienyl complexes of Mo(II): crystal structure of [MoCl(CO)2(η3-CH2C(COSePh)CCH2)(1,10-phenanthroline)]·0.5 CH2Cl2 (2002)
Journal Article

A series of organochalcogen ester substituted h3-butadienyl complexes of the type [MoCl(CO)2(h3-CH2C(COXR)C=CH2)(phen)] were prepared from the acyl chloride precursor and either thiols or selenols, and the structure of the first selenoester substitut... Read More about Synthesis and reactivity of organochalogen ester substituted η3-butadienyl complexes of Mo(II): crystal structure of [MoCl(CO)2(η3-CH2C(COSePh)CCH2)(1,10-phenanthroline)]·0.5 CH2Cl2.