Ex-situ exafs investigation of zeolite supported pt electrocatalyst structure

Yao, Jun; Yao, Yufeng

Abstract

The electrochemical performance of zeolite supported 1.5 wt% Pt electrocatalyst in fuel cell has been discussed in previous studies [1, 2]. This work will focus on investigating the influence of Pt loading and Pt deposition methods on Pt electrochemical performance and Pt particle size under different thermal treatment conditions. Both the 1.5 wt% and 5 wt% Pt loading on zeolite electrocatalyst were made in-house by Pt(NH3)4(NO3)2 salt or Pt(NH3)4(NO3)2/NH4NO3 salt with ion exchanged method and calcined at 350oC and then reduced at 400oC or direct reduced at 400oC, respectively. The cycle voltammetry measurement depicts a slightly high current change in hydride region for electrocatalyst under direct reduction at 400oC, with a shifted peak current towards positive potential region. This indicates that the energy level for hydrogen adsorption and desorption on Pt surface is higher in comparison to those electrocatalysts made by calcinations and reduction at 400oC. The extended X-ray adsorption fine spectroscopy measurement has revealed that the Pt nanoparticle size for electrocatalyst made by Pt(NH3)4(NO3)2/NH4NO3 or Pt(NH3)4(NO3)2 calcined and reduced at 400oC is smaller compared to those made by direct reduced at 400oC. The Pt nanoparticle size for 1.5 wt% Pt loading on zeolite is generally smaller than that for 5 wt% Pt loading electrocatalysts. The hydrogen spillover and surface conductance might be adopted to explain electrochemical performance presented by the Pt zeolite electrocatalyst.

• Presentation Conference Type: Conference Paper (unpublished)
• Conference Name: The Seventh International Symposium on Physics of Fluids (ISPF7)
• Start Date: Jun 12, 2017
• End Date: Jun 15, 2017
• Acceptance Date: Jun 12, 2017
• Publication Date: Jun 15, 2017
• Peer Reviewed: Peer Reviewed
• Public URL: https://uwe-repository.worktribe.com/output/886053
• Additional Information: Title of Conference or Conference Proceedings : The Seventh International Symposium on Physics of Fluids (ISPF7)