High catalytic activity and pollutants resistivity using Fe-AAPyr cathode catalyst for microbial fuel cell application

Atanassov, Plamen; Schuler, Andrew J.; Artyushkova, Kateryna; Babanova, Sofia; Stariha, Sarah; Villarrubia, Claudia W.Narvaez; Serov, Alexey; Santoro, Carlo

Abstract

© 2015, Macmillan Publishers Limited. All rights reserved. For the first time, a new generation of innovative non-platinum group metal catalysts based on iron and aminoantipyrine as precursor (Fe-AAPyr) has been utilized in a membraneless single-chamber microbial fuel cell (SCMFC) running on wastewater. Fe-AAPyr was used as an oxygen reduction catalyst in a passive gas-diffusion cathode and implemented in SCMFC design. This catalyst demonstrated better performance than platinum (Pt) during screening in "clean" conditions (PBS), and no degradation in performance during the operation in wastewater. The maximum power density generated by the SCMFC with Fe-AAPyr was 167±6μWcm-2 and remained stable over 16 days, while SCMFC with Pt decreased to 113±4μWcm-2 by day 13, achieving similar values of an activated carbon based cathode. The presence of S2- and SO42- showed insignificant decrease of ORR activity for the Fe-AAPyr. The reported results clearly demonstrate that Fe-AAPyr can be utilized in MFCs under the harsh conditions of wastewater.

• Journal Article Type: Article
• Acceptance Date: Sep 14, 2015
• Publication Date: Nov 13, 2015
• Deposit Date: Apr 25, 2018
• Publicly Available Date: Apr 25, 2018
• Journal: Scientific Reports
• Electronic ISSN: 2045-2322
• Publisher: Nature Research (part of Springer Nature)
• Peer Reviewed: Peer Reviewed
• Volume: 5
• DOI: https://doi.org/10.1038/srep16596
• Keywords: non-platinum group metal catalysts, Fe-AAPyr, single-chamber microbial fuel cell (SCMFC), wastewater
• Public URL: https://uwe-repository.worktribe.com/output/803296
• Publisher URL: http://dx.doi.org/10.1038/srep16596
• Contract Date: Apr 25, 2018