Outputs (2)

One pot synthesis of η3-butadienyl complexes of Mo(II) or W(II): Crystal structure of [MoCl(CO)2(η3-CH2C(CONHCH2Ctriple bondCH)Cdouble bondCH2)(2,2′-bipyridine)] (2006)
Journal Article

A one pot reaction of [M(CO)4L2] (M = Mo, L2 = 2,2′-bipyridine, 1,10-phenanthroline; M = W, L2 = 2,9-dimethyl-1,10-phenanthroline) with 1,4-dichloro-2-butyne and Ph4PCl was examined in chlorinated solvents over the range 40–129 °C. Production of eith... Read More about One pot synthesis of η3-butadienyl complexes of Mo(II) or W(II): Crystal structure of [MoCl(CO)2(η3-CH2C(CONHCH2Ctriple bondCH)Cdouble bondCH2)(2,2′-bipyridine)].

Effect of substituents on the molybdenum mediated carbonylation and methoxycarbonylation of dihaloalkynes (2006)
Journal Article

Dihaloalkynes of the type YCH(R)CtripleCCH(R)Y or YCMe2CtripleCCMe2Y (Y=Cl, Br, I) were prepared from their diol precursors and reacted with [Mo(CO)3(phen)Y]-. Formation and stability of the substituted products of the type [Mo(CO)2(h3-CH(R)C(COX)C=C... Read More about Effect of substituents on the molybdenum mediated carbonylation and methoxycarbonylation of dihaloalkynes.