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Preparation of graphene oxide/chitosan/ferrite nanocomposite for Chromium (VI) removal from aqueous solution

Samuel, Melvin S.; Shah, Sk. Sheriff; Subramaniyan, Vasudevan; Qureshi, Tanvir; Bhattacharya, Jayanta; Singh, N.D. Pradeep

Authors

Melvin S. Samuel

Sk. Sheriff Shah

Vasudevan Subramaniyan

Tanvir Qureshi

Jayanta Bhattacharya

N.D. Pradeep Singh



Abstract

A magnetically modified graphene oxide/chitosan/ferrite (GCF) nanocomposite material was synthesized and exploited for removal of Chromium(VI) from aqueous solution. The GCF nanocomposite material was characterized by powder-X-ray diffraction (powder-XRD), Fourier transform infrared spectroscopy (FT-IR), scanning electron microscope- energy dispersive X-ray (SEM-EDX) analysis, transmission electron microscopy (TEM) thermogravimetric analysis (TGA), UV–vis diffusive reflectance spectra and Brunauer–Emmett–Teller (BET) analysis. The effect of pH, adsorbent dose, contact time and initial Cr(VI) metal ion concentration were studied in batch process. The GCF nanocomposite material showed an adsorption capacity of 270.27 mg g−1 for Cr(VI) at pH 2.0. The adsorption mechanism of GCF adsorbent material was well described by Langmuir isotherm and pseudo second order kinetic model, with a high regression coefficient (

Citation

Samuel, M. S., Shah, S. S., Subramaniyan, V., Qureshi, T., Bhattacharya, J., & Singh, N. P. (2018). Preparation of graphene oxide/chitosan/ferrite nanocomposite for Chromium (VI) removal from aqueous solution. International Journal of Biological Macromolecules, 119, 540-547. https://doi.org/10.1016/j.ijbiomac.2018.07.052

Journal Article Type Article
Acceptance Date Jul 11, 2018
Online Publication Date Jul 31, 2018
Publication Date Nov 1, 2018
Deposit Date Sep 30, 2020
Journal International Journal of Biological Macromolecules
Print ISSN 0141-8130
Electronic ISSN 1879-0003
Publisher Elsevier
Peer Reviewed Peer Reviewed
Volume 119
Pages 540-547
DOI https://doi.org/10.1016/j.ijbiomac.2018.07.052
Keywords GCF nanocomposite material, Isotherms, Kinetics, Chromium(VI)
Public URL https://uwe-repository.worktribe.com/output/6726688
Publisher URL https://www.sciencedirect.com/science/article/abs/pii/S0141813018321287