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A structural and mechanistic investigation of the mono-O-phenylation of diols with BiPh3(OAc)2 (2002)
Journal Article
Coles, S. J., Costello, J. F., Hursthouse, M. B., & Smith, S. (2002). A structural and mechanistic investigation of the mono-O-phenylation of diols with BiPh3(OAc)2. Journal of Organometallic Chemistry, 662(1-2), 98-104. https://doi.org/10.1016/S0022-328X%2802%2901895-8

The mono-O-phenylation of enantiomerically pure pinanediol 2 using BiPh3(OAc)2 1 and the biphenyl-2,2′-ylenephenylbismuth analogue 9 has been investigated. It is postulated that reductive elimination at the trigonal bipyramidal bismuth (V) centre of... Read More about A structural and mechanistic investigation of the mono-O-phenylation of diols with BiPh3(OAc)2.