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Kinetic resolution of the chiral iron acetyl [Fe(η5-C5H5)(CO)(PPh3)COMe] (1993)
Journal Article
Prime, J. C., Hedgecock, C. J., Case-Green, S. C., Costello, J. F., Davies, S. G., Heaton, N., …Primes, J. C. (1993). Kinetic resolution of the chiral iron acetyl [Fe(η5-C5H5)(CO)(PPh3)COMe]. Journal of the Chemical Society, Chemical Communications, 21(21), 1621-1622. https://doi.org/10.1039/C39930001621

The chiral discrimination displayed between the enolate derived from (RS)-[Fe(η5-C5H5)(CO)(PPh3)COMe] and (1R)-(+)-camphor furnishes a practical route to homochiral (R)-[Fe(η5-C5H5)(CO)(PPh3)COMe] via a kinetic resolution protocol, while a retro-aldo... Read More about Kinetic resolution of the chiral iron acetyl [Fe(η5-C5H5)(CO)(PPh3)COMe].